Unfortunately, there are no Dolby plug-ins available. I'm not sure why; the patents expired long ago. Perhaps nobody's done it because the trademark Dolby B still applies, so they couldn't tell anyone what it did except in general terms -- like "Decodes the most common form of noise reduction on cassettes, if you know what we mean."
Getting maximum quality out of cassettes is about two things: tape path and azimuth. The cassette actually is the tape path, and usually sucks. In old casssettes, the pressure pad that holds the tape against the head is often deteriorated, so you don't have proper contact, and your highs are gone or fluctuating.
There are two possible solutions. The best is to use a 3-head Nakamichi deck, which pushes the pressure pad out of the way and maintains tension using dual-capstans. This also cuts way down on scrape flutter, which is good to do.
The second, if you don't have access to a Nak, is to transplant the tape into a new cassette. This will reap other benefits, including fresh slip sheets (the thin paper or plastic sheets above and below the tape), which will be less likely to squeak, and new roller bearings. I do this fairly frequently when transferring cassettes; I use the shells from Maxell XLII, which is still available at Walgreen's.
The other issue is azimuth. If the playback head's azimuth doesn't exactly match the azimuth of the head the tape was recorded with, your high frequencies disappear, and Dolby decoding makes it worse. Most cassette decks have an adjusting screw next to the head, visible when it's playing; turn the screw (with a non-magnetized screwdriver!) until you get maximum high-frequency response with the Dolby off. The most accurate way to do this is to sum the channels to mono; the point of maximum HF is much easier to find in mono. Just remember to go back to stereo for transferring!
The azimuth may be different on the two sides of the tape. In fact, it may be different on different cuts. If necessary, stop and tweak azimuth several times while transferring the tape.
Do these things, and you should get okay Dolby decoding in hardware. Provided, of course, that the machine the tapes were recorded on was set up properly to begin with. But at least this will let you get the most out of them.
Peace,
Paul