If the signal is symmetric and active outputs connecting that way will show you -6dB relative to the actual signal. If the signal is transformer coupled you have not connected one side of the transformer so you would see no movement on the meter.
Balanced connections are measured between pins 2 and 3, that is the only defined voltage to give an accurate measurement of the signal level.
Do you have a link to the driver board schematic? If the driver board is active you may be required to connect in a specific way for proper operation.
Generate a sine wave signal using whatever means you have available (signal generator, sound card, in a pinch a synthesizer might do) and adjust the level until the voltmeter reads 0.775V between pins 2 and 3. That is 0 dBu. Keep in mind your voltmeter may have limited frequency range over which it is accurate, so use primarily low frequency signals (any meter should be accurate with 50Hz or 60Hz since that is a primary application for volt meters). If you have a higher quality meter then it should have a user guide indicating accuracy at other frequencies.