I own a 1964 AC30, which I have worked on a little bit from time to time.
In Vox amps, the 25/25 caps are typically for cathode bypass (gain), these might do with replacing (can get rid of hiss). If you are not familiar with valves, follow the circuitry up to the valve pins and learn what the pin numbers represent for a given valve. Be very careful with the turret boards as they are very fragile in these old amps. I would, if possible, leave all of the polyester caps alone, even if reading a little high. Most likely all of the carbon comp resistors are reading +20% but I would probably leave them to. Guitar amps are pretty tolerate when it comes to component values. Replacing valves is a good idea (you are doing this). If it were my amp, I would leave all of the audio circuitry resistors and capacitors well alone and keep it original as possible. As a previous poster alluded to, it may depend on whether it matters to you to maintain the amp in original form.
Good luck and please let us know what it sounds like when you get it going. I built an AC15-type head that was based on my three favourite Vox channels (Normal channel (with a variable tone cap mod a bit like some Matchless amps), Top Boost and EF86 with bright switch). Even this is too loud for me now. As I get older I tend to play amps with lower & lower wattage (Champ is my current favourite). I'm thinking of using building a little (Vox-styled) push pull amp with EL91s next!