> a simple rectified power supply to try to learn the software, but I couldn't get the Multimeter to read the DC output, although it would work fine reading either an unrectified AC or just a DC voltage source...
This goes to the root of SPICE (the engine under all these toys). A DC analysis ignores AC. An AC analysis really only computes infinitesimal signals, not reality. You must use TRAN (transient) analysis mode. (I've seen that in TINA but didn't try it.)
That's actually one of the harder circuits to SPICE. Whydoncha start with some batteries and resistors? Your questions elsewhere suggest you don't have Ohms Law intuitively internalized. You need to be able to glance at a simple circuit and know about how the currents and voltages fall. I'm not sure SPICE will help or become a crutch.
Another good exercise is an AC source with some R, C and L, and plot frequency response. For me, this is where SPICE shines: doing the tedious complex floating math. I never believe SPICE unless it agrees with my wild-approximation guess, but if I say "about 1KHz" and SPICE says "1.26543*10^3" then SPICE is probably exactly right (for ideal theoretical parts).