For someone less knowledgeable in dummy terms: If I need to reach a capacitance of 187.5uf, is it better to recalculate the crossover to hit a more standard value, put a 6.8uf in parallel with a 180uf or use three identical 62uf in parallel?
Parallel capacitors. Anything that works. Be aware that rolled up capacitors are quite microphonic. I prefer to use metal encased oil filled MKP "Motor Run" capacitors for crossovers. For extra points get NOS PCP Oil filled "toxic waste" ones at maximum discount.
Also, make sure your calculations are corrects. Drivers are not resistors. Especially dome tweeters have strong resonances that can interfere with crossovers. Cone drivers in case of midranges again will have a strong fundamental resonance usually not far from the crossover frequency and all drivers are more or less inductive.
On top, drivers have their own acoustic roll off, unless they remain flat in response at least two octaves either side of the crossover frequency.
As drivers are usually not coincident, there will phasing issues at frequencies with a wavelength longer than ~ 1/4 of the spacing between drivers.
As drivers often end up near reflective barriers to sound (floor, ceiling, walls to sides and behind this usually needs to be taken into account.
Crossover components are not ideal either. Especially the resistance of inductors needs to be accounted for.
All of this means a simple textbook calculated crossovers never work. Never, ever. They cannot, because they start from incorrect assumptions.
With a Pro-Audio system we even in the 80's had active crossovers with steep slopes (8th order LR) and 3rd octave band EQ's to correct problems. Even so, it turned out that random "mix'n'match" systems rarely worked well and systems properly designed with a system controller proved superior.
So again, before you worry what components to buy at the MINIMUM use makers datasheets and a speaker simulator like vituixcad to see if things stand a remote chance of working well.
Once you got your chosen drivers, mechanical arrangement and crossover to work IN THEORY, buy the drivers, build the box and MEASURE your drivers in the box.
Then and ONLY then can you make a first cut crossover to test and measure as well as listen in real life.
There you may measure or perceive problems, because your simulation did not simulate enough off axis cases etc et al, or you optimised one set of parameters that do not matter a lot while compromising others that actually do.
A solid sim is not a reliable good turnout, but without one you are doing what may be described as: "looking for a small black cat in a large dark room"...
Thor