bibi said:
How does a rectifier tube affect the sound of an amp other than changing the operating voltage?
How does any tube change the sound? How do capacitors change the sound? They all do.
This point was amazingly illustrated to me when I participated in a tube rolling session in a class I took years ago when we all built single-ended class A hi-fi line stages in the class. Towards the end of the semester, twenty or so of us gathered in the instructor's garage and we tried different tubes, including the rectifier. It was a very controlled listening session.
There were no right or wrong answers. Sometimes we heard things a little differently. But most of the time the differences were obvious, plain and clear and everyone in the room agreed. The rectifiers changed the tone. Just like your choice of caps do. The power supply becomes the audio signal, remember. One member brought in a Mullard GZ34 he had, and we all agreed it sounded amazing. When he told us the cost of those now, it made sense -- other people hear the difference too and are willing to pay for it.
I was a skeptic before these experiences. You really need to try it yourself. I would guess some circuits will reflect these tones better than others, and being a musician helped me tremendously in the class -- there were two students who couldn't hear any differences because they were inexperienced listening to music and were unfamiliar with subtle shifts in tone, character timbre. The instructor was not a musician, and he heard everything that I heard, and that was one reason he found the tube rolling session so interesting -- it illustrated how different tubes change tones and he wanted less experienced students to be exposed to it. To my ears, as a musician, the results were night and day. It's one of the main reasons I'm interested in DIY, because I'm able to shape the sound of my own gear and recordings.
...or at least I have fun learning and trying...