Diode checker.
You see the arrow on the transistor symbol, for emitter-base diode. The collector-base is another diode. Collector-emitter does not act as a diode. So poking your diode checker at the transistor, all six ways, you will find two diodes. You know the tab points at the Emitter. So the collector should be clear.
Or find the data-sheet. For that '2222, or for any metal TO-92 can (they all de same).
If you still need a clue: base is in center.
Now for that PCB....
A properly docced kit should tell you. (Especially since plastic-blob transistors are NOT all the same pin-out.) However, you can sort it. Q1 has a 100r to E, a 1K5 to B, and a 22K to C. Q2 has similarly distict resistors on each leg. You even have those numbers printed-on. (Albeit hidden under the bodies.) (And if they could print resistor values, why not E B and C?)