> shocks, is this stray capacitance through the transformer or is this having to do with a hot chassis
Amp with one 6V6 is "surely" not literal hot-chassis.(*)
Your shocks may be the "small" stray capacitance in the PT.
Or it could be failed insulation in the PT.
WHY haven't you installed a proper modern 3-pin plug already??
You know you should.
It would divert stray-capacitance current.
If you have a hard-fault in the insulation (some people hardly notice straight 110), the 3rd-pin would blow a fuse and PROVE you have a problem. (Minor, since any Champ replacement PT will do the job.)
Hot-chassis guitar amps have tubes like 50L6, 50A6, 25L6, 35L6--- the two biggest tubes will be 25V-70V heater, the first two digits. While such a line-up "could" still be transformer isolated, the whole reason for such oddball voltages is so they (and you) can be strung-up directly across the 110V wall outlet.
CJ's toy is odd in that ONE of the tubes "is" transformer isolated heater. This is not even a half-assed attempt at Safety (maybe third-assed). I believe this type was made UnApproved as soon as UL could re-write their standards to keep-up with over-clever designers and marketers.