Of course, which is exactly why I asked what the reference level is, i.e. relative to what reference voltage.
Sound Devices makes it more difficult than necessary to figure out the reference level, but the spec sheet for your interface says that the maximum input level for line input is 28 dBu, and the minimum line input gain is -20 dB, implying that for 0dB gain 0 dB FS is 8 dBu. I think, it is not entirely clear how the gain staging is setup, whether the max input spec is for 0 dB gain or minimum gain.
Assuming the max input is specified at minimum gain, for mic input the maximum input is 14 dBu, but minimum gain is 6 dB, so again 0dB would be 8 dBu. That is consistent, so I'll go with that.
8 dBu is 1.95V RMS. In your original spectrogram the high frequency noise floor was around -100 dB, and the 220 Hz noise peaked at -80 dB. It is not clear from your screenshot what FFT parameters were used, so hard to compare to normalized per Hz values, but just using the raw values, that -80 dB peak would be around 0.2mV. That is pretty low for a basic switcher. It would be good to know where it is coming from, but considering that the manufacturer noise plus ripple spec is 120mV peak-to-peak, you probably won't get a lot of help from Cui trying to get even lower than that.
Clearly audible where? At the output of the audio circuit being tested? Are you trying to power a really simple transistor circuit of some kind? Any kind of op-amp based audio circuit is going to have quite high power supply rejection at 220Hz, at least 80dB, which would put that -80 dBu peak on the raw power supply at around -160 dBu at the output of the audio circuit.
Of course a single ended transistor circuit with no feedback is going to have essentially 0 PSRR, so it matters what kind of circuit you are powering.
It also is important to verify that you are actually measuring what you think you are, so checking your setup with a pair of batteries, and other known high quality power supplies would be useful, as well as the switchers you have under varying load conditions (i.e. put some different sized resistors on the output so you can see if the noise varies with the amount of current supplied).