It is a little tricky in the rude tube arrangement to do an additional hi-Z output of a useful voltage level for a guitar amp.
Taking signal off the line amp tube output will cause loading effects for the balanced output for sure.
But it could be done using an attenuation network. I's just that the main output will be compromised.
You could also try taking off the line driver tube grid with a suitable attenuation network. You'll get some thing working
but again it will certainly compromise the performance of the line amp.
Another possibility is taking off from the cathode of the line amp tube with a suitable network.
Or even the cathode of the 2nd tube for that matter.
That would work but the output Z would be on the low side.
Perhaps you can make a network to increase the Z.
I think that would be the least bad option.
Bottom line is I don't think it can be done without big compromises.
It really needs an additional tube or transformer or even (god forbid) a fet or so
Good luck