Failure of these tantalum rail caps may be related to gradual failure of the primary electrolytic caps at the front end of a power supply leading to increased ripple which may cause the tantalums to reach critical internal temperature.
Also when any electronic device runs hot, after power off as it cools and the ambient temperature drops, because of air flow through the vents it will attract moisture from the air to the cooling boards and the components on them. The reliability of the solid tantalum capacitor is also heavily influenced by environmental conditions such as humidity and temperature. Moisture can penetrate the polymer encapsulating material, degrade the characteristics of the solid electrolyte, cathode attachment materials, and tantalum pentoxide dielectric, and cause the capacitor to fail - these devices are not hermetically sealed. Thus a capacitor which has absorbed moisture as it cools or is operating in an high humidity environment and is presented with a turn-on surge or heavy ripple it may blow. High relative humidity and high temperature both affect water diffusion, but apparently increased ripple voltage in 85°/85% testing causes tantalum capacitor characteristics to weaken and capacitors to fail.
Water molecules can be absorbed or adsorbed by hygroscopic materials, which have moieties that can form hydrogen bonds with water or metal cations that can form a coordinate covalent bond with the oxygen atoms in water. Several polymers used in electronics, such as epoxy resins, polycarbonate and poly (methyl methacrylate), are examples of hygroscopic materials. The saturated amount of absorbed moisture by such a material is proportional to the relative humidity.
Absorption of moisture over time leads to the gradual degradation of susceptible components such as tantalums.
Also when any electronic device runs hot, after power off as it cools and the ambient temperature drops, because of air flow through the vents it will attract moisture from the air to the cooling boards and the components on them. The reliability of the solid tantalum capacitor is also heavily influenced by environmental conditions such as humidity and temperature. Moisture can penetrate the polymer encapsulating material, degrade the characteristics of the solid electrolyte, cathode attachment materials, and tantalum pentoxide dielectric, and cause the capacitor to fail - these devices are not hermetically sealed. Thus a capacitor which has absorbed moisture as it cools or is operating in an high humidity environment and is presented with a turn-on surge or heavy ripple it may blow. High relative humidity and high temperature both affect water diffusion, but apparently increased ripple voltage in 85°/85% testing causes tantalum capacitor characteristics to weaken and capacitors to fail.
Water molecules can be absorbed or adsorbed by hygroscopic materials, which have moieties that can form hydrogen bonds with water or metal cations that can form a coordinate covalent bond with the oxygen atoms in water. Several polymers used in electronics, such as epoxy resins, polycarbonate and poly (methyl methacrylate), are examples of hygroscopic materials. The saturated amount of absorbed moisture by such a material is proportional to the relative humidity.
Absorption of moisture over time leads to the gradual degradation of susceptible components such as tantalums.